Pulley came yesterday. Alignment seems fine, no change from before.
I used a piece of rope to get a rough idea of required belt length and it seems I'll need a belt at about 42" (1066mm). Hope I have time tonight to stop at the parts store.
The belt does sit down in the new pulley a bit, yielding an effective diameter of 3 9/16". If I did the math right, at a 750rpm idle, the alternator should be spinning at about 1150 rpm.
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